Synthesis of tetrasubstituted alkenes via metathesis.
نویسنده
چکیده
Fully substituted olefin generation via metathesis is presented. Catalyst development, optimization of reaction conditions and substrate screening are included. In addition, asymmetric alkene metathesis, the cross metathesis reaction for this transformation and its application in natural products will be discussed.
منابع مشابه
Ruthenium-catalyzed ring-closing metathesis to form tetrasubstituted olefins.
[structure: see text]. Increased efficiency for ring-closing metathesis to form tetrasubstituted olefins using N-heterocyclic carbene ligated ruthenium catalysts was achieved by reducing the size of the substituents at the ortho positions of the N-bound aryl rings.
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ورودعنوان ژورنال:
- Molecules
دوره 17 3 شماره
صفحات -
تاریخ انتشار 2012